Noncovalent porphyrin-functionalized single-walled carbon nanotubes in solution and the formation of porphyrin-nanotube nanocomposites
Noncovalent porphyrin-functionalized single-walled carbon nanotubes in solution and the formation of porphyrin-nanotube nanocomposites
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DOI：
10.1016/s0009-2614(03)01329-0
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发表时间：
2003-09-12
影响因子：
2.8
通讯作者：
Nakashima, N
中科院分区：
文献类型：
--
作者：
Murakami, H;Nomura, T;Nakashima, N
卟啉是功能性染料，具有各种独特的物理（照片），化学和生物学特性。我们报告了第一个发现，卟啉分子溶解了有机溶液中的单壁碳纳米管（SWNT），并且可以将SWNTS-PORPHYRIN杂交纳米材料与溶液分开。原子力显微镜研究表明，溶液中共存的单独溶解纳米管和捆绑的纳米管。固体纯化的SWNT（p-SWNT） - 孢子蛋白纳米材料很容易与P-SWNTS-PORPHYRIN溶液分离，并且该纳米材料可在DMF中重新分解。其荧光光谱的测量结果证明了溶液中纳米管侧壁和卟啉分子之间的相互作用。 （c）2003 Elsevier B.V.保留所有权利。
Porphyrins are functional dyes with a variety of unique physical (photo physical), chemical and biological properties. We report on the first finding that porphyrin molecules dissolve single-walled carbon nanotubes (SWNTs) in organic solutions and that the SWNTs-porphyrin hybrid nanomaterials can be separated from the solutions. Atomic force microscope investigation revealed that both individually dissolved nanotubes and bundled nanotubes coexisted in the solution. The solid purified SWNTs (p-SWNTs)-porphyrin nanomaterials were readily separated from the p-SWNTs-porphyrin solution, and this nanomaterial was re-dissolvable in DMF. Measurements of its fluorescence spectrum gave evidence for the interaction between the nanotube sidewall and porphyrin molecules in solution. (C) 2003 Elsevier B.V. All rights reserved.