Towards allosteric receptors – synthesis of β-cyclodextrin-functionalised 2,2’-bipyridines and their metal complexes
Towards allosteric receptors – synthesis of β-cyclodextrin-functionalised 2,2’-bipyridines and their metal complexes
复制标题
面向变构受体——β-环糊精功能化2,2-联吡啶及其金属配合物的合成
DOI：
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发表时间：
2014
影响因子：
2.7
通讯作者：
A. Lützen
中科院分区：
文献类型：
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作者：
C. Kremer;G. Schnakenburg;A. Lützen
本文中，我们提出了三个新的2，2 '-联吡啶，其以不同的取代模式携带两个β-环糊精部分。当与锌（II）或铜（I）离子（或其络合物）配位时，这些化合物经历构象变化并在“开放”和“封闭”形式之间切换，从而使环糊精部分彼此结合或分离。
Herein, we present three new 2,2’-bipyridines that carry two β-cyclodextrin moieties in different substitution patterns. When coordinated by zinc(II) or copper(I) ions (or their complexes), these compounds undergo conformational changes and switch between “open” and “closed” forms and thereby bringing together or separating the cyclodextrin moieties from each other.