A spherical molecule with a carbon-free Ih-C80 topological framework [Ein sphärisches Molekül mit einem Kohlenstoff-freien Ih-C80-topologischen Gerüst]
A spherical molecule with a carbon-free Ih-C80 topological framework [Ein sphärisches Molekül mit einem Kohlenstoff-freien Ih-C80-topologischen Gerüst]
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具有无碳 Ih-C80 拓扑框架的球形分子 [Einm Kohlenstoff-freien Ih-C80-topologischen Gerüst]
DOI:
10.1002/ange.200900342
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发表时间:
2009
影响因子:
1.8
通讯作者:
Eugenia V. Peresypkina
中科院分区:
文献类型:
--
作者:
M. Scheer;A. Schindler;Christian Gröger;Alexander V. Virovets;Eugenia V. Peresypkina
The complete encapsulation of ortho-carborane by a fullerene-like building-block system consisting of pentaphosphaferrocene and CuICl leads to the formation of the spherical supermolecule C2B10H12§[{Cp*Fe(5-P5)}12(CuCl)20]. This product of template-controlled aggregation represents the first example of a carbon-free C80 analogue possessing icosahedral symmetry.