Phosphines and related P-C-bonded compounds
Phosphines and related P-C-bonded compounds
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DOI：
10.1039/9781849734875-00001
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发表时间：
2012-01-01
期刊：
影响因子：
--
通讯作者：
Allen, D. W.
中科院分区：
文献类型：
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作者：
Allen, D. W.
本章涵盖了2013年发表的与上述领域相关的文献，除了2012年发表在较难获得的期刊上的几篇论文，这些论文于2013年在《化学文摘》中曝光。2013年发表的论文数量与2012年相似，在选择引用的出版物时也必须继续有所选择。尽管如此，希望已经注意到最重要的事态发展。在过去的一年里，又发表了大量的评论文章，本报告各节引用了其中许多文章。在催化中使用广泛的三价磷配体仍然是传统P-C键合膦化学的主要驱动力（以及三价磷酸衍生物，在本卷其他地方详细介绍）。再次，这里回顾的文献的一个值得注意的特点是大量的论文报道的膦的反应性的研究，特别是那些涉及亲核攻击在一个亲电底物的碳原子。最近的有机磷化学的一般性评论有关的催化领域提供了新的联萘基为基础的膦和亚磷酸酯配体，1纯手性砷/磷为基础的配体，2和磷为基础的树枝状聚合物的合成的发展，无论是在端基或其结构内的正电荷的覆盖面。3其他一般性评论包括氟烷基膦的化学概况4和通过碳中心自由基均裂取代磷来合成有机磷化合物的方法。5
This chapter covers the literature published during 2013 relating to the above area, apart from a few papers from 2012 in less accessible journals which came to light in Chemical Abstracts in 2013. The number of papers published in 2013 is similar to that in 2012 and again it has been necessary to continue to be selective in the choice of publications cited. Nevertheless, it is hoped that the most significant developments have been noted. The past year has again seen the publication of a considerable number of review articles and many of these are cited in the various sections of this report. The use of a wide range of tervalent phosphorus ligands in catalysis continues to be a major driver in the chemistry of traditional P–C-bonded phosphines (and also that of tervalent phosphorus acid derivatives, covered in detail elsewhere in this volume). Once again, a noteworthy feature of the literature reviewed here is the large number of papers reporting studies of the reactivity of phosphines, in particular those involving nucleophilic attack at a carbon atom of an electrophilic substrate. Recent general reviews of organophosphorus chemistry relevant to the catalysis area have provided coverage of developments in the synthesis of new binaphthyl-based phosphine and phosphite ligands, 1 homochiral arsenic-/phosphorus-based ligands, 2 and phosphorus-based dendrimers having positive charges either on terminal groups or inside their structures. 3 Other general reviews include a survey of the chemistry of fluoroalkylphosphines4 and synthetic approaches to organophosphorus compounds by homolytic substitution at phosphorus with carbon-centred radicals. 5