Facile assembly of an unusual lead borate with different cluster building units via a hydrothermal process.
Facile assembly of an unusual lead borate with different cluster building units via a hydrothermal process.
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DOI：
10.1021/ic400752y
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发表时间：
2013-05
影响因子：
4.6
通讯作者：
Han-Rui Tian;Wen‐Hua Wang;Yan-E Gao;T. Deng;Jiayang Wang;Yun-long Feng;Jian-Wen Cheng
中科院分区：
文献类型：
--
作者：
Han-Rui Tian;Wen‐Hua Wang;Yan-E Gao;T. Deng;Jiayang Wang;Yun-long Feng;Jian-Wen Cheng
以Pb（BO 2）2·H2O为B和Pb的源，通过简单的水热反应合成了第一个5，9-连接的硼酸铅化合物Pb 6 B4 O 11（OH）2（1）。化合物1以正交晶系空间群Pnma结晶。晶体结构是由B4 O 9和Pb 6 O 4的不同簇结构单元组成。化合物1具有3.24eV的光学带隙。
Pb(BO2)2·H2O as sources of B and Pb via a simple hydrothermal process provided the first binodal 5,9-connected lead borate, Pb6B4O11(OH)2 (1). Compound 1 crystallizes in the orthorhombic space group Pnma. The crystal structure is composed of different cluster building units of B4O9 and Pb6O4. Compound 1 has an optical band gap of 3.24 eV.