Syntheses and Hydrogen Desorption Properties of Metal-Borohydrides M(BH4)n (M=Mg, Sc, Zr, Ti, and Zn; n=2–4) as Advanced Hydrogen Storage Materials
Syntheses and Hydrogen Desorption Properties of Metal-Borohydrides M(BH4)n (M=Mg, Sc, Zr, Ti, and Zn; n=2–4) as Advanced Hydrogen Storage Materials
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DOI：
10.2320/matertrans.47.1898
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发表时间：
2006-08
影响因子：
1.2
通讯作者：
Y. Nakamori;Haiwen Li;K. Miwa;S. Towata;S. Orimo
中科院分区：
文献类型：
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作者：
Y. Nakamori;Haiwen Li;K. Miwa;S. Towata;S. Orimo
采用机械球磨工艺合成了金属硼氢化物M(BH4)n(M？Mg，Sc，Zr，Ti，Zn；n？2{4)：MCln：nLiBH4/nNaBH4！M(BH4)n-nLiCl/nNaCl.然后用气相色谱、质谱联用热重分析法研究了M(BH4)n的热脱附性能。结果表明，氢气的脱附
Metal-borohydrides M(BH4)n (M ¼ Mg, Sc, Zr, Ti, and Zn; n ¼ 2{4) were synthesized by mechanical milling process according to the following reaction; MCln þ nLiBH4/nNaBH4 ! M(BH4)n þ nLiCl/nNaCl. Then the thermal desorption properties of M(BH4)n were investigated by gas-chromatography and mass-spectroscopy combined with thermogravimetry. The results indicate that the hydrogen desorption