Analysis of the Topology of the Chromophore Binding Pocket of Phytochromes by Variation of the Chromophore Substitution Pattern.
Analysis of the Topology of the Chromophore Binding Pocket of Phytochromes by Variation of the Chromophore Substitution Pattern.
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通过发色团取代模式的变化分析光敏色素的发色团结合袋的拓扑结构。
DOI：
10.1002/1521-3773(20010316)40:6
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发表时间：
2001
影响因子：
--
通讯作者：
K. Schaffner
中科院分区：
文献类型：
--
作者：
Uwe Robben;I. Lindner;W. Gärtner;K. Schaffner
在LiE化合物（E族14元素Si±Pb）的同源系列中，LiSi[1,2]和LiGe[3,4]在常压（NP）下为Zintl相[5,6]，而LiSn[7]和LiPb[8,9]属于金属间相。由于电荷转移Li SiÀ和Li GeÀ，这些Zintl相中的SiÀ和GeÀ离子与第15族元素呈等价电子，并建立了具有三个同核键的mgga型结构[10]的三维三坐标网。然而，在金属间化合物LiSn[7]和LiPb中，[8,9]
In the homologous series of LiE compounds (E Group 14 elements Si±Pb), LiSi [1, 2] and LiGe [3, 4] are Zintl phases at normal pressure (NP),[5, 6] but LiSn [7] and LiPb [8, 9] belong to the class of intermetallic phases. Owing to a charge transfer Li SiÀ and Li GeÀ, the SiÀ and the GeÀ ions in these Zintl phases are isovalence-electronic to the elements of Group 15, and build up the three-dimensional three-coordinate net of the MgGa-type structure [10] with three homonuclear bonds. However, in the intermetallic compounds LiSn [7] and LiPb,[8, 9]