Photodegradation of Target Oligosaccharides by Light-Activated Small Molecules
Photodegradation of Target Oligosaccharides by Light-Activated Small Molecules
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DOI：
10.1002/anie.201005161
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发表时间：
2010-01-01
影响因子：
16.6
通讯作者：
Toshima, Kazunobu
中科院分区：
文献类型：
--
作者：
Takahashi, Daisuke;Hirono, Shingo;Toshima, Kazunobu
Shine on，shine on：所设计的蒽醌/硼酸杂合物1选择性地引起具有β-D-呋喃半乳糖苷残基的寡糖的降解，所述β-D-呋喃半乳糖苷残基是分枝杆菌细胞壁中的独特组分。在不存在任何添加剂和中性条件下，使用长波长UV辐射实现降解。
Shine on, shine on: The designed anthraquinone/boronic acid hybrid 1 selectively caused the degradation of oligosaccharides that have a β-D-galactofuranoside residue, which is a unique component in mycobacterial cell walls. Degradation was achieved using long-wavelength UV radiation in the absence of any additives and under neutral conditions.