A ladder type iron(II) coordination polymer with cooperative spin transition
A ladder type iron(II) coordination polymer with cooperative spin transition
复制标题
DOI：
10.1039/c2cc35109a
复制
发表时间：
2012-01-01
影响因子：
4.9
通讯作者：
Weber, Birgit
中科院分区：
文献类型：
--
作者：
Bauer, Wolfgang;Schlamp, Stephan;Weber, Birgit
根据晶体工程的概念，合成了梯形一维配位聚合物，旨在改善铁(II)配合物的自旋交叉性能。如果使用刚性连接件，则观察到较宽的磁滞回线(34K)。报道了一维铁(II)阶梯的第一个X射线结构。
Ladder type 1D coordination polymers were synthesised with the aim to improve the spin crossover properties of the iron(II) complexes following the concepts of crystal engineering. A wide hysteresis loop (34 K) was observed if rigid linkers were used. The first X-ray structure for a 1D iron(II) ladder is reported.