trans-Dimethano-lbis(1,1,1-trifluoro-5,5-dimethyl-hexane-2,4-dionato)zinc(II).
trans-Dimethano-lbis(1,1,1-trifluoro-5,5-dimethyl-hexane-2,4-dionato)zinc(II).
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DOI：
10.1107/s1600536808037963
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发表时间：
2008-12-10
期刊：
影响因子：
--
通讯作者：
Leskiw BD
中科院分区：
文献类型：
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作者：
Hunter GO;Zeller M;Leskiw BD
标题化合物[Zn(C8H10F3O2)2(ch40)2]是一种二甲醇配位锌配合物，其乙酰丙酮衍生物1,1,1-三氟-5,5-二甲基己烷-2,4-二酸酯。二-β-二酮酸配合物位于晶体倒置中心，其结构与Co类似物相同。该配合物为八面体，基本没有变形，甲醇分子彼此处于反位。β-二酮酸盐和ZnO4单元的平面相互倾斜18.64（10）°。O - h⋯O氢键在甲醇羟基和相邻的二酮酸O原子之间形成沿[100]运行的链。
The title compound, [Zn(C8H10F3O2)2(CH4O)2], is a dimethanol coordinated zinc complex with the acetyl acetonate derivative 1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionate. The bis-β-diketonate complex, which is isostructural with its Co analogue, is located on a crystallographic inversion center. The complex is octahedral with basically no distortion, and the methanol molecules are in trans positions with respect to one another. The planes of the β-diketonate and the ZnO4 unit are tilted by 18.64 (10)° against each other. O—H⋯O hydrogen bonds between the methanol hydroxyl groups and neighboring diketonate O atoms create chains running along [100].