Hydrothermal Reaction of Glucose and Glycine as Model Compounds of Biomass (特集:バイオマス資源のエネルギー利用)
Hydrothermal Reaction of Glucose and Glycine as Model Compounds of Biomass (特集:バイオマス資源のエネルギー利用)
复制标题
生物质模型化合物葡萄糖和甘氨酸的水热反应（专题：生物质资源的能源利用）
DOI：
10.3775/jie.83.794
复制
发表时间：
2004
影响因子：
8.4
通讯作者：
Y. Matsumura
中科院分区：
文献类型：
--
作者：
T. Minowa;S. Inoue;T. Hanaoka;Y. Matsumura
葡萄糖和甘氨酸作为生物质模型化合物在150和350°C之间的热压水中反应。基于反应温度，检查作为气体、焦炭、油和水产物的产物分布。美拉德产物类黑精在200°C以上分解，在水溶液中产生炭、气体、氨和分解产物。焦炭在150 - 200°C的低反应温度范围内形成，而油在250°C以上形成。提出的总体反应方案如下。
Glucose and glycine as biomass model compounds were reacted in hot-compressed water between 150 and 350°C. The product distribution as gas, char, oil and aqueous products was examined based on the reaction temperature. The Maillard products, melanoidin, were decomposed over 200°C to produce the char, gas, ammonia and decomposed products in aqueous solution. The char was formed in the low reaction temperature-range from 150 to 200°C, while the oil was formed over 250°C. The overall reaction scheme was proposed as follows.