Spin Dynamics Study in Conducting Polymers by Magnetic Resonance

Spin Dynamics Study in Conducting Polymers by Magnetic Resonance
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通过磁共振研究导电聚合物的自旋动力学

DOI:
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发表时间:
1995
期刊:
影响因子:
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通讯作者:
K. Mizoguchi
K. Mizoguchi
中科院分区:
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文献类型:
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作者:
K. Mizoguchi

文献摘要

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相似文献

我们已经应用自旋动力学技术的导电聚合物,特别是,与ESR方法,并研究微观输运性质的准一维(Q1D)聚合物链。该技术是获得本征输运性质微观信息的独特方法,因为宏观电阻率主要受到微晶之间界面区域电性质的限制。本文将详细介绍该方法的原理和应用。本文还将讨论ESR与1H NMR的区别,并强调其各自的特征。
We have applied the spin dynamics technique to conducting polymers, in particular, with the ESR method, and investigated microscopic transport properties in a quasi-one-dimensional (Q1D) polymer chain. This technique is a unique method for obtaining microscopic information on intrinsic transport properties, because macroscopic resistivity is mainly limited by electrical properties of interfacial regions between microcrystals. In this article, the principles and applications of this method will be reviewed in detail. The difference between ESR applied here and 1H NMR will also be discussed, and each characteristic feature will be stressed.