ON THE CHEMISTRY OF BINDING-SITES .1. FAST THERMAL BREAKING AND FORMATION OF A B-N BOND IN 2-(AMINOMETHYL)BENZENEBORONATES
ON THE CHEMISTRY OF BINDING-SITES .1. FAST THERMAL BREAKING AND FORMATION OF A B-N BOND IN 2-(AMINOMETHYL)BENZENEBORONATES
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DOI：
10.1002/cber.19811141021
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发表时间：
1981-01-01
期刊：
影响因子：
--
通讯作者：
WULFF, G
中科院分区：
文献类型：
--
作者：
BURGEMEISTER, T;GROBEEINSLER, R;WULFF, G
标题化合物1至6（表1）由1H、11 B和15 N NMR位移显示，形成分子内B-N键，根据1N和13 C NMR，该键经常断裂（δ G数学图像= 40至54 kJ/mol，表2）并重新形成。
The Title compounds 1 to 6 (Table 1) are shown by 1H, 11B, and 15N NMR shifts to fom an intramolecular B - N bond which, according to 1N and 13C NMR, is frequently broken (δ G math image = 40 to 54 kJ/mol, Table 2) and re-formed.