Platinum substituted boroles
Platinum substituted boroles
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DOI：
10.1039/b923652j
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发表时间：
2010-01-01
影响因子：
4.9
通讯作者：
Brenner, Peter
中科院分区：
文献类型：
--
作者：
Braunschweig, Holger;Chiu, Ching-Wen;Brenner, Peter
成功制备了前所未有的1-金属硼孔[(Cy3P)(2)Pt(Cl)(BC4Ph4)](1)及其t形阳离子衍生物(2)。对硼结合金属配合物的电子学进行微调，导致1-金属硼穴的最低电子跃迁能发生显著变化。
The unprecedented 1-metalloborole [(Cy3P)(2)Pt(Cl)(BC4Ph4)] (1) and its T-shaped cationic derivative (2) were successfully prepared and structurally characterized. Fine-tuning the electronics of the boron-bound metal complex leads to a significant change in the lowest electronic transition energy of the 1-metalloboroles.