Electrophilic Aromatic Substitution of Arenes with CO2 Mediated by R3SiB(C6F5)4
Electrophilic Aromatic Substitution of Arenes with CO2 Mediated by R3SiB(C6F5)4
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DOI：
10.1246/cl.2012.913
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发表时间：
2012-09-05
影响因子：
1.6
通讯作者：
Hattori, Tetsutaro
中科院分区：
文献类型：
--
作者：
Konno, Megumi;Chiba, Masafumi;Hattori, Tetsutaro
芳烃的Friedel Craft型羧化反应是通过用硼酸硅活化二氧化碳来实现的。该反应比我们之前报道的AIX(3)/R3SiX介导的羧化反应具有更广泛的底物适用性。
The Friedel Crafts-type carboxylation of arenes has been achieved by activating CO2 with silylium borates. The reaction exhibits broader substrate applicability than does our previously reported AIX(3)/R3SiX-mediated carboxylation.