Uniqueness and Versatility of Iminopyrrolyl Ligands for Transition Metal Complexes
Uniqueness and Versatility of Iminopyrrolyl Ligands for Transition Metal Complexes
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DOI：
10.1002/chin.200604227
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发表时间：
2005-10
期刊：
影响因子：
--
通讯作者：
K. Mashima;H. Tsurugi
中科院分区：
文献类型：
--
作者：
K. Mashima;H. Tsurugi
含亚氨基吡咯单元的氮基配体由于其与过渡金属的灵活络合作用而引起了人们的关注。由于空间和电子的需求可以很容易地引入到亚氨基吡咯单元，各种各样的配体已被设计和合成。本文综述了多齿亚氨基吡咯类过渡金属配合物的合成、结构特点及其催化活性，特别是α-烯烃聚合的研究进展。
Nitrogen-based ligands containing an iminopyrrole unit have recently attracted attention because of their flexible complexation to transition metals. Since steric and electronic demands can be readily introduced to the iminopyrrole unit, a wide variety of ligand has been designed and synthesized. In this contribution, we briefly review synthetic and structural features of transition metal complexes with the multidentate iminopyrrolyl ligands and their catalytic activity, especially polymerization of α-olefins.