Synthesis of rare earth metal complexes based on phenol ether bidentate ligands and polymerization of 2-vinylpyridine

Synthesis of rare earth metal complexes based on phenol ether bidentate ligands and polymerization of 2-vinylpyridine
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酚醚二齿配体稀土金属配合物的合成及2-乙烯基吡啶的聚合

DOI:
10.1016/j.poly.2021.115219
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发表时间:
2021-07
期刊:
影响因子:
2.6
通讯作者:
Zhu Yong-Zheng
Zhu Yong-Zheng
中科院分区:
化学3区
文献类型:
--
作者:
Han Cui-Ting;Yan Chao;Xu Tie-Qi;Zhu Yong-Zheng

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本课题组在前期工作中发现,四齿酚醚稀土催化剂对2-乙烯基吡啶聚合具有高度的等选择性。为了探索醚链对2-乙烯基吡啶聚合的影响,合成了6个结构相似的双齿酚酯稀土配合物。探讨了2-VP的聚合反应,讨论了金属中心和不同配体对聚合反应的影响。
In previous work, our group found that tetradentate phenol ether rare earth catalysts show highly isoselectivity for 2-vinylpyridine polymerization. In order to explore the influence of ether chain on 2-vinylpyridine polymerization, six rare earth complexes with bidentate phenol ester ligands with similar structures were synthesized. Polymerizations of 2-VP were also explored, the effects of metal centers and different kinds of ligands on the polymerization were also discussed.
金属尺寸对同选择性 2-乙烯基吡啶聚合的影响
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