Conjugated Radical Cation Dimerization‐Driven Generation of Supramolecular Architectures
Conjugated Radical Cation Dimerization‐Driven Generation of Supramolecular Architectures
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DOI：
10.1002/chin.201535273
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发表时间：
2015-09
期刊：
影响因子：
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通讯作者：
Lan Chen;Yun-Chang Zhang;Wei-Kun Wang;Jia Tian;Liang Zhang;Hui Wang;Dan‐Wei Zhang;Zhanting Li
中科院分区：
文献类型：
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作者：
Lan Chen;Yun-Chang Zhang;Wei-Kun Wang;Jia Tian;Liang Zhang;Hui Wang;Dan‐Wei Zhang;Zhanting Li
本文总结了利用共轭自由基阳离子二聚（CRCD）构建新型单分子（例如折叠体）和超分子有序结构（例如三维超分子聚合物和二维超分子有机框架）的最新进展。特别是，四硫富瓦烯和4,4'-联吡啶亚基的堆积或二聚化受到了重视，并讨论了增强其自由基阳离子二聚体稳定性的方法。
This paper summarizes the recent advance in utilizing conjugated radical cation dimerization (CRCD) for constructing new unimolecular, such as foldamers, and supramolecular ordered structures, such as three-dimensional supramolecular polymers and two-dimensional supramolecular organic framework. Particularly, the stacking or dimerization of tetrathiafulvalene and 4,4′-dipyridium subunits has been highlighted, and the approaches for enhancing the stability of their radical cation dimers have been discussed.