Interference effects on (e, 2e) electron momentum profiles of CF4.
Interference effects on (e, 2e) electron momentum profiles of CF4.
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DOI:
10.1103/physrevlett.108.173201
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发表时间:
2012-04
影响因子:
8.6
通讯作者:
N. Watanabe;Xiangjun Chen;M. Takahashi
中科院分区:
文献类型:
--
作者:
N. Watanabe;Xiangjun Chen;M. Takahashi
Interference effects on electron momentum profiles have been studied using binary (e, 2e) spectroscopy for the three outermost molecular orbitals of CF(4), which are composed of the F 2p nonbonding atomic orbitals. An analysis of the measured spherically averaged electron momentum densities has clearly shown the presence of oscillatory structures having direct information about the internuclear distance between the F atoms. Furthermore, it is demonstrated that the phase of the oscillatory structures depends upon the orientation in space of the constituent atomic orbitals.