Dielectric Methods of Studying the Chemical Bond and the Concept of Electronegativity

Dielectric Methods of Studying the Chemical Bond and the Concept of Electronegativity
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DOI:
10.1070/rc1982v051n07abeh002900
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发表时间:
1982-07
影响因子:
7.7
通讯作者:
S. Batsanov
S. Batsanov
中科院分区:
化学2区
文献类型:
--
作者:
S. Batsanov

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考虑了分子和晶体极化的历史和当代理论,并对分子化合物中的偶极矩和键离子性以及晶体中原子的有效电荷进行了系统的调查。从电负性概念的角度对这些结果作了解释。考虑了晶体中原子的有效价和配位数的观点。参考文献207。
The history and contemporary theories of the polarisation of molecules and crystals are considered and a systematic survey is given of dipole moments and bond ionicities in molecular chemical compounds and also of the effective charges of atoms in crystals. An interpretation of these results is given from the standpoint of the electronegativity concept. Views concerning the effective valencies and coordination numbers of atoms in crystals are considered. Bibliography of 207 references.