Spiral Eu(iii) coordination polymers with circularly polarized luminescence

Spiral Eu(iii) coordination polymers with circularly polarized luminescence
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DOI:
10.1039/c8cc05147j
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发表时间:
2018-09-28
影响因子:
4.9
通讯作者:
Ishii, Kazuyuki
Ishii, Kazuyuki
中科院分区:
化学2区
文献类型:
--
作者:
Hasegawa, Yasuchika;Miura, Yui;Ishii, Kazuyuki

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一种螺旋型手性Eu(iii)配位聚合物显示出很强的发光(发射量子产率phi(f-f)= 57%,光敏能量转移效率(sens)= 53%)和有效CD和CPL性质(g(CPL)= 0.17),当与固态单核手性Eu(iii)配合物(phi(f-f)= 36%,(sens)= 14%,和g(CPL)= 0.09)。
A spiral-type chiral Eu(iii) coordination polymer showed strong luminescence (emission quantum yield phi(f-f) = 57% and photosensitized energy transfer efficiency (sens) = 53%) and effective CD and CPL properties (g(CPL) = 0.17) when compared with a mono-nuclear chiral Eu(iii) complex in the solid state (phi(f-f) = 36%, (sens) = 14%, and g(CPL) = 0.09).