C-H bond activation by water on a palladium or platinum metal surface

C-H bond activation by water on a palladium or platinum metal surface
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DOI:
10.1055/s-2007-983738
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发表时间:
2007-07-03
影响因子:
2.6
通讯作者:
Yamamoto, Mitsuru
Yamamoto, Mitsuru
中科院分区:
化学4区
文献类型:
--
作者:
Matsubara, Seijiro;Asano, Keisuke;Yamamoto, Mitsuru

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在水热条件下,水分子在钯或铂金属表面部分裂解,形成活性铂物种。该物种是C-H键功能化的有效物种,可用于H/D交换反应、CC成键反应和C-N成键反应。
A water molecule is partially cleaved on a palladium or platinum metal surface under hydrothermal conditions to form an active platinum species. The species is effective for C-H bond functionalization which can be applied for H/D-exchange reactions, CC bond-forming reactions, and C-N bond-forming reactions.