Catalyst self-adaptation in conjugate addition to nitroalkenes and nitroacrylates: instant chirality control in diphenylmethane-based phosphoramidite ligands.
Catalyst self-adaptation in conjugate addition to nitroalkenes and nitroacrylates: instant chirality control in diphenylmethane-based phosphoramidite ligands.
复制标题
DOI：
10.1021/ja710340n
复制
发表时间：
2008-03
影响因子：
15
通讯作者：
Kazuki Wakabayashi;K. Aikawa;S. Kawauchi;K. Mikami
中科院分区：
文献类型：
--
作者：
Kazuki Wakabayashi;K. Aikawa;S. Kawauchi;K. Mikami
硫代二苯基甲烷基亚磷酰胺配体(A)在铜催化硝基烯烃和硝基丙烯酸酯的共轭加成反应中具有很高的催化活性和对映体选择性，这是由于A的瞬时手性控制。
The tropos diphenylmethane-based phosphoramidite ligand (A) provides high catalytic activity and enantioselectivity in the Cu catalysis of conjugate addition to nitroalkenes and nitroacrylate, by virtue of instant chirality control in A.