Meso–meso directly linked dipyrrolyl ligand dimer that shows the formation of metal-coordination polymers

Meso–meso directly linked dipyrrolyl ligand dimer that shows the formation of metal-coordination polymers
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DOI:
10.1142/s1088424612501295
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发表时间:
2013-02
影响因子:
1.5
通讯作者:
H. Maeda;Hiroaki Kobayashi;R. Akuta
H. Maeda;Hiroaki Kobayashi;R. Akuta
中科院分区:
化学4区
文献类型:
--
作者:
H. Maeda;Hiroaki Kobayashi;R. Akuta

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一种直接在内消旋位置连接的新型二吡咯金属配位配体二聚体显示出 ZnII 桥联配位聚合物的形成,并通过 C-C 键形成和伴随的质子迁移在溶液中自发转变为内消旋-内消旋和单 β-β-稠合四吡咯分子。
A novel dipyrrolyl metal-coordination ligand dimer directly connected at the meso positions showed the formation of a ZnII-bridged coordination polymer and the spontaneous transformation to a meso–meso- and singly β–β-fused tetrapyrrolyl molecule in solution by C–C bond formation and concomitant proton migration.