Partial oxidation of propane to acrylic acid at a Mo-V-Te-Nb-oxide catalyst
Partial oxidation of propane to acrylic acid at a Mo-V-Te-Nb-oxide catalyst
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DOI：
10.1016/j.apcata.2004.02.019
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发表时间：
2004-07-20
影响因子：
5.5
通讯作者：
Rosowski, F
中科院分区：
文献类型：
--
作者：
Balcells, E;Borgmeier, F;Rosowski, F
在 360 < T（摄氏度）< 420 的温度范围内，在多组分氧化催化剂上研究了丙烷的部分氧化。动力学测量是在具有分布式局部采样的一体化操作固定床反应器中进行的。进料中的氧-丙烷比率在 1.5 < x(O2)/x(丙烷) < 4 范围内变化，并且水含量增加至 50 vol.%。结果可以通过并行和连续的一级反应网络来定量描述。 (C) 2004 Elsevier B.V. 保留所有权利。
The partial oxidation of propane has been investigated at a multicomponent oxidic catalyst in the temperature range 360 < T (degreesC) < 420. The kinetic measurements were carried out in an integrally operated fixed bed reactor with distributed local sampling. The oxygen-propane ratio in the feed has been varied in the range 1.5 < x(O2)/x(propane) < 4 and the water content was increased up to 50 vol.%. The results can be described quantitatively by a network of parallel and consecutive first order reactions. (C) 2004 Elsevier B.V. All rights reserved.