First-row transition metal catalyzed reduction of carbonyl functionalities: a mechanistic perspective
First-row transition metal catalyzed reduction of carbonyl functionalities: a mechanistic perspective
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DOI：
10.1039/c002942d
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发表时间：
2010-08-28
影响因子：
4
通讯作者：
Guan, Hairong
中科院分区：
文献类型：
--
作者：
Chakraborty, Sumit;Guan, Hairong
使用第一行过渡金属地段羰基官能团的催化还原在均相催化中已变得越来越重要。这一观点探讨了这些还原反应的机理方面，重点是金属络合物和底物之间的各种相互作用。即用二氢化物（或二氢）络合物催化。用一氢化物络合物催化。金属-配体双功能催化和催化涉及离子机制，讨论了最近的例子突出
The use of first-row transition metals lot the catalytic reduction of carbonyl functionalities has become increasingly important in homogeneous catalysis This Perspective examines the mechanistic aspects of these reduction reactions, with a focus on various interactions between metal complexes and substrates Four different types of catalytic pathways. namely catalysis with dihydride (or dihydrogen) complexes. catalysis with monohydride complexes. metal-ligand bifunctional catalysis. and catalysis involving ionic mechanisms, are discussed with recent examples highlighted