Preparation of α-zirconium phosphate nanoplatelets with wide variations in aspect ratios
Preparation of α-zirconium phosphate nanoplatelets with wide variations in aspect ratios
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DOI：
10.1039/b604054c
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发表时间：
2007-01-01
影响因子：
3.3
通讯作者：
Clearfield, Abraham
中科院分区：
文献类型：
--
作者：
Sun, Luyi;Boo, Woong J.;Clearfield, Abraham
通过三种不同的方法制备了合成的α-磷酸锆层结构。通过控制反应物浓度、温度、压力和使用络合剂，制备了长径比变化较大的α-ZrP。合成的α-ZrP可以很容易地被胺插层，然后在环氧树脂中剥离，制备聚合物纳米复合材料。含有具有宽高宽比变化的剥离型α-ZrP纳米片的纳米复合材料可以作为模型系统来研究聚合物纳米复合材料的结构-性能关系。
Synthetic alpha-zirconium phosphate (alpha-ZrP) layer structures have been prepared via three different approaches. By controlling the concentration of reactants, temperature, pressure, and using a complexing agent, alpha-ZrP with a wide variation in aspect ratios has been prepared. Synthetic alpha-ZrP can be easily intercalated by amines and then exfoliated in epoxy to prepare polymer nanocomposites. Nanocomposites that contain exfoliated alpha-ZrP nanoplatelets with wide variations in aspect ratios can be utilized as model systems to study the structure-property relationship in polymer nanocomposites.