Synthesis and Applications of Trifluoromethylphosphines
Synthesis and Applications of Trifluoromethylphosphines
复制标题
DOI：
10.1002/ejoc.202301169
复制
发表时间：
2024-01-12
影响因子：
2.8
通讯作者：
Li，Suhua
中科院分区：
文献类型：
--
作者：
Zhang，Shouzhi;Fan，Wu;Li，Suhua
三氟甲基膦(TFMPhos)是一种罕见的膦，具有独特的电子性质，导致不寻常的反应活性，例如能够促进还原消除步骤或作为三氟甲基化试剂。这篇概念性文章综述了这种叔膦的合成方法的最新进展，以及它们的实际应用。
Trifluoromethylphosphines (TFMPhos) represent a rare kind of phosphine with unique electronic properties that result in unusual reactivities, such as the ability to promote a reductive elimination step or as a trifluoromethylation reagent. This concept article summarizes current developments in methods for synthesizing this tertiary phosphine, as well as their practical applications.