Investigation on transient relaxation in Ag-BaO composite thin film with pump supercontinuum-probe technique

Investigation on transient relaxation in Ag-BaO composite thin film with pump supercontinuum-probe technique
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泵浦超连续谱探针技术研究Ag-BaO复合薄膜的瞬态弛豫

DOI:
10.1088/0022-3727/35/12/307
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发表时间:
2002-06
期刊:
Journal of Physics D, Vol. 35, (2002) 1326-1329.
影响因子:
--
通讯作者:
Jinlei Wu
Jinlei Wu
中科院分区:
其他
文献类型:
--
作者:
Qifeng Zhang;Danling Wang;Qihuang Gong;Jinlei Wu

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利用泵浦超连续谱探测技术,在450 ~ 800 nm波长范围内,测量了Ag-BaO薄膜的光学瞬态吸收谱,时间分辨率为130 fs。观察到银纳米粒子费米能级附近的电子被激发到非平衡态,然后又回到平衡态的光学超快弛豫过程。衰减时间是指数拟合和变化从4到0.67 ps取决于探测波长。银中电子的未占态X '4的峰值估计位于费米能级以上1.47 eV处。
Optical transient absorption spectra of Ag-BaO thin film were detected in the wavelength range from 450 to 800 nm by the pump supercontinuum-probe technique with 130 fs time resolution. The optical ultrafast relaxation, in which the electrons near the Fermi level of silver nanoparticles were excited to non-equilibrium state and then returned to equilibrium state, was observed. The decay times were exponentially fitted and varied from 4 to 0.67 ps depending on the probe wavelength. The peak unoccupied state, X'4, of electrons in silver was estimated to locate at 1.47 eV above the Fermi level.
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