Photocontrolled nucleobase binding to an organometallic RuII arene complex
Photocontrolled nucleobase binding to an organometallic RuII arene complex
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DOI：
10.1039/b914153g
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发表时间：
2009-01-01
影响因子：
4.9
通讯作者：
Sadler, Peter J.
中科院分区：
文献类型：
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作者：
Betanzos-Lara, Soledad;Salassa, Luca;Sadler, Peter J.
配合物[(p-cym)Ru(bpm)(py)][PF6](2)（其中p-cym =对伞花烯，bpm = 2,2'-联嘧啶和py =吡啶）是第一个钌（II）芳烃配合物，当可见光激发时可以选择性地光解单齿配体（py）并形成能够结合DNA碱基的活性水基衍生物。
The complex [(p-cym)Ru(bpm)(py)][PF6](2) (where p-cym = para-cymene, bpm = 2,2'-bipyrimidine and py = pyridine) is the first ruthenium(II) arene complex that can selectively photodissociate a monodentate ligand (py) when excited with visible light and form a reactive aqua derivative able to bind to a DNA base.