Polarization spectroscopy as a probe of Raman optical activity
Polarization spectroscopy as a probe of Raman optical activity
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偏振光谱作为拉曼光学活性的探针
DOI：
10.1063/1.443296
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发表时间：
1982
影响因子：
4.4
通讯作者：
B. A. Garetz
中科院分区：
文献类型：
--
作者：
J. Oudar;C. Minot;B. A. Garetz
偏振敏感相干反斯托克斯拉曼光谱和拉曼诱导克尔效应被认为是研究拉曼光学活性的可能技术。半经典地导出了包括磁偶极和电四极相互作用的广义非线性光学极化率。这些条款可以区分从电偶极子条款，通过其特殊的对称性，和几个偏振配置进行了讨论，这似乎是适当的拉曼旋光性的研究。这些可能构成一个方便的替代传统技术的圆差分拉曼散射测量此属性。
Polarization‐sensitive coherent antistokes Raman spectroscopy and the Raman‐induced Kerr effect are considered as possible techniques for investigating Raman optical activity. Generalized nonlinear optical susceptibilities including both magnetic dipole and electric quadrupole interactions are derived semiclassically. These terms can be distinguished from electric dipole terms through their particular symmetry, and several polarization configurations are discussed which seem appropriate to the study of Raman optical activity. These might constitute a convenient alternative to the conventional technique of circular differential Raman scattering for measuring this property.