Cyclic (alkyl)(amino)carbene gold(I) complexes: A synthetic and structural investigation
Cyclic (alkyl)(amino)carbene gold(I) complexes: A synthetic and structural investigation
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DOI：
10.1016/j.jorganchem.2008.01.026
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发表时间：
2008-04-15
影响因子：
2.3
通讯作者：
Bertrand, Guy
中科院分区：
文献类型：
--
作者：
Frey, Guido D.;Dewhurst, Rian D.;Bertrand, Guy
通过Au(SMe2)与游离卡宾a-e反应，合成了一系列Au(CaAc)(Cl)[CaAc=环烷基(氨基)卡宾](1)和[Au(CaAc)(2)](+)[X](-)(X=Cl，AuCl2)(2)系列单卡宾金(I)配合物，并用单晶X-射线衍射法(1a，1b，2d，2e)对其结构进行了表征。此外，还合成了两个新的自由环(烷基)(氨基)卡宾(c和e)。(C)2008爱思唯尔B.V.保留所有权利。
A series of mono- and dicarbene gold(I) complexes of types Au(CAAC)(Cl) [CAAC = cyclic (alkyl)(amino)carbene] (1) and [Au(CAAC)(2)](+) [X](-) (X = Cl, AuCl2) (2) have been prepared through reaction of AuCl(SMe2) with free carbenes a-e, and structurally characterized by single X-ray diffraction studies (1a, 1b, 2d, 2e). In addition two new free cyclic (alkyl)(amino) carbenes (c and e) have been synthesized. (C) 2008 Elsevier B.V. All rights reserved.