Ionothermal synthesis of crystalline metal phosphites using multifunctional protic ionic liquids
Ionothermal synthesis of crystalline metal phosphites using multifunctional protic ionic liquids
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DOI：
10.1039/d0ce01182g
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发表时间：
2020-09
期刊：
影响因子：
3.1
通讯作者：
Ting Li;Yumei Mao;Y. Qi;Hongmei Zeng;Guohong Zou;Zhien Lin
中科院分区：
文献类型：
--
作者：
Ting Li;Yumei Mao;Y. Qi;Hongmei Zeng;Guohong Zou;Zhien Lin
采用多功能质子离子液体离子热法合成了两种新的结晶亚磷酸金属盐（SCU-9和SCU-17）。SCU-9具有包含有机模板剂和有机配体的三维结构。SCU-17是一种以有机阳离子为模板的混合价化合物，具有层状结构。该化合物在沸水中耐水解，并在95%相对湿度下显示出有趣的质子传导行为。
Two new crystalline metal phosphites (SCU-9 and SCU-17) were ionothermally prepared using multifunctional protic ionic liquids. SCU-9 has a three-dimensional structure containing both organic templates and organic ligands. SCU-17 is a mixed-valence compound with a layered structure templated by organic cations. This compound is resistant to hydrolysis in boiling water and shows interesting proton-conducting behaviors under 95% relative humidity.