Recent Advances in Voltammetry.
Recent Advances in Voltammetry.
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DOI：
10.1002/open.201500042
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发表时间：
2015-06
期刊：
影响因子：
2.3
通讯作者：
Molina A
中科院分区：
文献类型：
--
作者：
Batchelor-McAuley C;Kätelhön E;Barnes EO;Compton RG;Laborda E;Molina A
本文综述和评价了近年来伏安法在理论和实践方面的进展。在过去的十年里，实验的建模和模拟水平的转变已经取得了重大进展，使得电化学技术可以得到充分的发展，并应用于具有独特复杂性的真实的化学问题。本文综述的主题领域：多步电化学过程，伏安法在离子液体中，电子转移理论（巴特勒-沃尔默和马库斯-嘘）的发展和解释，伏安脉冲技术的进展，随机随机游走模型的扩散，迁移的影响下的条件下的低支持，伏安法在粗糙和多孔电极，和纳米粒子电化学。后一领域的审查包括纳米粒子修饰电极的研究，包括溶出伏安法和新技术的“纳米冲击”。
Recent progress in the theory and practice of voltammetry is surveyed and evaluated. The transformation over the last decade of the level of modelling and simulation of experiments has realised major advances such that electrochemical techniques can be fully developed and applied to real chemical problems of distinct complexity. This review focuses on the topic areas of: multistep electrochemical processes, voltammetry in ionic liquids, the development and interpretation of theories of electron transfer (Butler–Volmer and Marcus–Hush), advances in voltammetric pulse techniques, stochastic random walk models of diffusion, the influence of migration under conditions of low support, voltammetry at rough and porous electrodes, and nanoparticle electrochemistry. The review of the latter field encompasses both the study of nanoparticle-modified electrodes, including stripping voltammetry and the new technique of ‘nano-impacts’.