RAMAN AND INFRARED STUDY OF SOLID BENZYL ALCOHOL

RAMAN AND INFRARED STUDY OF SOLID BENZYL ALCOHOL
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DOI:
10.1002/jrs.1250250206
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发表时间:
1994-02-01
影响因子:
2.5
通讯作者:
TORRIE, BH
TORRIE, BH
中科院分区:
化学3区
文献类型:
--
作者:
PRYSTUPA, DA;ANDERSON, A;TORRIE, BH

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本文首次报道了固体苯甲醇及其两种部分氘化同系物的拉曼光谱和红外光谱。根据同位素波数位移,确定了苯甲醇的内部振动模式和晶格模式。固体苯甲醇在低温下的光谱与有序的非中心对称结构相一致,在单元胞中至少有四个分子。
Raman and infrared spectra of solid benzyl alcohol and two partially deuterated homologues are reported for the first time. The internal vibrational modes and lattice modes of benzyl alcohol are assigned on the basis of isotopic wavenumber shifts. The spectra of solid benzyl alcohol at low temperatures are shown to be consistent with an ordered non-centrosymmetric structure, with at least four molecules in the unit cell.