VII. On a new series of compounds derived from ammonia and its analogues
VII. On a new series of compounds derived from ammonia and its analogues
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通讯作者：
E. Frankland
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作者：
E. Frankland
尽管锌乙基及其同系物现在众所周知能够用乙基等取代负电元素，然而，几乎没有人能预料到，同一种试剂会发生几乎相反性质的取代反应; 2然而，我发现乙基锌能够除去氨及其类似物中的一个氢原子，并能用锌取代它，从而形成一系列的化合物，这使我们强烈地想起钾的酰胺和氮化物。由此可以表达产生下述化合物的该反应的一般性质。
Although zincethyl and its homologues are now well known to be capable of replacing electro-negative elements by ethyl, &c., yet it could scarcely have been anticipated, that substitutions of an almost opposite character would be effected by the same reagent; nevertheless I find that zincethyl is capable of removing one of the atoms of hydrogen in ammonia and its analogues, and of replacing it by zinc, thus forming a series of bodies which strongly remind us of the amide and nitride of potassium. The general nature of this reaction by which the compounds described below are produced, may be thus expressed.