Porous metal-organic frameworks as platforms for functional applications
Porous metal-organic frameworks as platforms for functional applications
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DOI：
10.1039/c0cc05419d
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发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
Xu, Qiang
中科院分区：
文献类型：
--
作者：
Jiang, Hai-Long;Xu, Qiang
金属有机骨架(MOF)又称配位聚合物，是由金属离子或金属离子簇合物和桥联有机连接物构成的一类新型结晶性多孔材料。MOF具有可调节的孔和功能，通常具有非常高的比表面积。多孔MOF的潜在应用领域非常广泛，它们的应用大多与孔的大小、形状和结构/环境有关。在这篇专题文章中，我们综述了多孔MOF作为平台在吸附和分离、多相催化、金属纳米颗粒的载体/宿主基质以及作为模板/纳米反应器制备新材料等功能应用方面的最新进展。
Metal-organic frameworks (MOFs), also known as coordination polymers, have emerged as a new class of crystalline porous materials, which are constructed from metal ions or metal ion clusters and bridging organic linkers. MOFs have tunable pores and functionalities, and usually exhibit very high surface areas. The potential applications of porous MOFs cover a broad range of fields and most of their applications are related to pore sizes, shapes and structures/environments. In this feature article, we provide an overview of the recent developments of porous MOFs as platforms in the functional applications of sorption and separation, heterogeneous catalysis, as supports/host matrices for metal nanoparticles, and as templates/nanoreactors for new material preparation.