Cationic molybdenum(IV)- and tungsten(IV)-iridium(III) complexes with hydride and eta5:eta1-cyclopentadienyl bridging ligands. Syntheses and x-ray crystal structure of [(eta5-C5H5)M(mu-H)2(mu-(eta5:eta1-C5H4))IrH(PMePh2)2][BPh4] (M = Mo and W)
Cationic molybdenum(IV)- and tungsten(IV)-iridium(III) complexes with hydride and eta5:eta1-cyclopentadienyl bridging ligands. Syntheses and x-ray crystal structure of [(eta5-C5H5)M(mu-H)2(mu-(eta5:eta1-C5H4))IrH(PMePh2)2][BPh4] (M = Mo and W)
复制标题
阳离子钼(IV)-和钨(IV)-铱(III)与氢化物和eta5:eta1-环戊二烯基桥连配体的配合物。
DOI：
10.1021/om00140a005
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发表时间：
1986
期刊：
影响因子：
2.8
通讯作者：
L. Venanzi
中科院分区：
文献类型：
--
作者：
A. Albinati;A. Togni;L. Venanzi
PMePh2) 被测定。两种化合物同晶，属于Cc空间群；晶胞尺寸：o= 10.736 (1) A，b= 18.872 (2) A，c= 26.060 (2) Á，ß= 101.43 (1)，V= 5175 (1) A3，对于 [6c][BPh4]，Z= 4，o= 10.724 (2) A，b= 18.834 (2) [7c][BPh4] 的 A, c= 26.091 (3) A, ß= 101.44 (3), V= 5165 (2) A3 和 Z= 4，结构分别精炼至 R= 0.045 和 0.052。 [6c][BPh4] 中的氢化物配体通过最小二乘法定位和细化。两种阳离子的几何形状相似；有趣的区别是金属-金属距离（W-Ir= 2.706 (1) 和 Mo-Ir= 2.641 (1) A）。然而，3与[IrH2(丙酮)2(PCy3)2]+(le)的反应遵循不同的明确定义的化学计量，给出6e、[WH3-(^S-C5H5)2]+(11)和[IrH5(PCy3)2](13e)。
PMePh2) were determined. The two compounds are isomorphous and belong to space group Cc; unit-cell dimensions: o= 10.736 (1) A, b= 18.872 (2) A, c= 26.060 (2) Á, ß= 101.43 (1), V= 5175 (1) A3, and Z= 4 for [6c][BPh4] and o= 10.724 (2) A, b= 18.834 (2) A, c= 26.091 (3) A, ß= 101.44 (3), V= 5165 (2) A3, and Z= 4 for [7c][BPh4], The structures were refined to R= 0.045 and 0.052, respectively. The hydride ligands in [6c][BPh4] were located and refined by least squares. The geometries of the two cations are similar; the interesting difference being the metal-metal distance (W-Ir= 2.706 (1) and Mo-Ir= 2.641 (1) A). The reaction of 3 with [IrH2 (acetone) 2 (PCy3) 2]+(le), however, follows a different well-defined stoichiometrygiving 6e,[WH3-(^ S-C5H5) 2]+(11), and [IrH5 (PCy3) 2](13e).