Optically Reconfigurable Chiral Microspheres of Self-Organized Helical Superstructures with Handedness Inversion.

Optically Reconfigurable Chiral Microspheres of Self-Organized Helical Superstructures with Handedness Inversion.
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DOI:
10.1039/c7mh00644f
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发表时间:
2017
期刊:
影响因子:
13.3
通讯作者:
Li Q
Li Q
中科院分区:
材料科学1区
文献类型:
--
作者:
Wang L;Chen D;Gutierrez-Cuevas KG;Bisoyi HK;Fan J;Zola RS;Li G;Urbas AM;Bunning TJ;Weitz DA;Li Q

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采用毛细管微流控技术制备了具有动态手性的自组织螺旋超结构单分散光可重构手性微球。研究了不同构型微球之间的光驱动手性可逆变换,并证明了微球之间的光可调RGB光子交叉通信。在低手性胆甾体微球中生动地观察到伴随手性反转现象的光驱动动态结构转变,并在高手性胆甾体微球中成功地证明了微球之间的光学可调红、绿、蓝(RGB)光子交叉通信。
Optically reconfigurable monodisperse chiral microspheres of self-organized helical superstructures with dynamic chirality were fabricated via a capillary-based microfluidic technique. Light-driven handedness-invertible transformations between different configurations of microspheres were vividly observed and optically tunable RGB photonic cross-communications among the microspheres were demonstrated. Light-driven dynamic structural transformations accompanied by handedness inversion phenomenon were vividly observed in the cholesteric microspheres with low chirality, and optically tunable red, green, and blue (RGB) photonic cross-communications among the microspheres were successfully demonstrated in the systems with high chirality.
DOI: 10.1002/anie.201606895
发表时间: 2016-10-10
期刊: Angewandte Chemie (International ed. in English)
影响因子: --
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