Copolymerization of Vinyl Acetate with Ethylene by Palladium/Alkylphosphine-Sulfonate Catalysts
Copolymerization of Vinyl Acetate with Ethylene by Palladium/Alkylphosphine-Sulfonate Catalysts
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DOI：
10.1021/ja9050839
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发表时间：
2009-10-21
影响因子：
15
通讯作者：
Nozaki, Kyoko
中科院分区：
文献类型：
--
作者：
Ito, Shingo;Munakata, Kagehiro;Nozaki, Kyoko
用含烷基膦-磺酸盐配体的新型钯配合物实现了乙酸乙烯酯(VAc)与乙烯的配位共聚，得到了具有链上CH2CH(OAc)单元的线型共聚物。
Coordination copolymenzation of vinyl acetate (VAc) with ethylene, leading to linear copolymers that possess in-chain -CH2CH(OAc)- units, has been accomplished using novel palladium complexes bearing alkylphosphine-sulfonate ligands.