Nanochannels for Supramolecular Organisation of Dyes
Nanochannels for Supramolecular Organisation of Dyes
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DOI：
10.2533/chimia.2007.626
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发表时间：
2007
期刊：
影响因子：
1.2
通讯作者：
A. Devaux;Katsiaryna Lutkouskaya;G. Calzaferri;Le-Quyenh Dieu;D. Brühwiler;L. Cola;T. Torres
中科院分区：
文献类型：
--
作者：
A. Devaux;Katsiaryna Lutkouskaya;G. Calzaferri;Le-Quyenh Dieu;D. Brühwiler;L. Cola;T. Torres
超分子组织的分子，复合物或集群是一个富有成效的概念，系统的设计表现出特定的宏观性能。将客体物质包封到主体材料的孔或通道中是制备新型化学和光学材料的具有挑战性的方法。L沸石是有机染料超分子组装的理想载体。通过将沸石L晶体排列成密集堆积的定向单层或通过经由与晶体边缘结合的分子将它们与环境界面连接，可以实现结构有序的新层次。这些概念在这里进行审查，以及一些潜在的应用。
The supramolecular organisation of molecules, complexes or clusters is a fruitful concept for the design of systems exhibiting specific macroscopic properties. The encapsulation of guest species into the pores or channels of host materials presents a challenging approach to the preparation of novel chemical and optical materials. Zeolite L has been shown to be an ideal host for the supramolecular organisation of organic dyes. A new hierarchy of structural ordering can be achieved by either arranging the zeolite L crystals into densely packed, oriented monolayers or by interfacing them to the environment via molecules bound to the edges of the crystals. These concepts are reviewed here, as well as some potential applications.