Copper-mediated cyanation of indoles and electron-rich arenes using DMF as a single surrogate.
Copper-mediated cyanation of indoles and electron-rich arenes using DMF as a single surrogate.
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DOI：
10.1039/c5ob01244a
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发表时间：
2015-07
影响因子：
3.2
通讯作者：
Lianpeng Zhang;P. Lu;Yanguang Wang
中科院分区：
文献类型：
--
作者：
Lianpeng Zhang;P. Lu;Yanguang Wang
实现了以DMF为单一替代物的铜离子介导的吲哚氰化反应。该方法同样适用于富电子芳烃和芳醛的氰化反应。芳香醛是吲哚和富电子芳烃氰化级联反应的关键中间体。
The copper-mediated cyanation of indoles with DMF as a single surrogate has been realized. This approach could be applied for the cyanation of some electron-rich arenes and aryl aldehydes as well. Aryl aldehydes were demonstrated to be the key intermediates in the cascade process of cyanation of indoles and electron-rich arenes.