An investigation of the optical properties of Tb3+-doped phosphate glasses for green fiber laser

An investigation of the optical properties of Tb3+-doped phosphate glasses for green fiber laser
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DOI:
10.1016/j.optmat.2012.01.031
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发表时间:
2012-05
期刊:
影响因子:
3.9
通讯作者:
Liaolin Zhang;M. Peng;G. Dong;J. Qiu
Liaolin Zhang;M. Peng;G. Dong;J. Qiu
中科院分区:
材料科学3区
文献类型:
--
作者:
Liaolin Zhang;M. Peng;G. Dong;J. Qiu

文献摘要

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对掺Tb ~(3+)磷酸盐玻璃的热稳定性、吸收光谱、静态和瞬态发光光谱、量子效率等进行了测试和分析。当Tb ~(3+)浓度达到15mol%时,没有观察到荧光猝灭现象。掺10mol%Tb ~(3+)的磷酸盐玻璃的外量子效率为78%,是目前文献报道的最高外量子效率。玻璃的ΔT(Tx-Tg)值较大,约为340°C,保证了玻璃在拉丝过程中的热稳定性,并成功拉制出掺Tb 3+磷酸盐玻璃纤维。
Thermal stabilities, absorption spectra, static and transient luminescence spectra, quantum efficiencies were measured and analyzed for the phosphate glasses doped with Tb3+. No fluorescence quenching was observed even when Tb3+concentration reached 15mol%. The external quantum efficiency of phosphate glass containing 10mol%Tb3+was measured to be 78%, which is the highest up to date compared with other Tb3+-doped materials reported in previous literatures. The large value of ΔT (Tx–Tg) of the glasses was about 340°C, which guarantees the thermal stability of the glasses against crystallization during the fiber drawing process, and Tb3+-doped phosphate glass fibers have been successfully drawn.