A rhenium tricarbonyl 4'-oxo-terpy trimer as a luminescent molecular vessel with a removable silver stopper.

A rhenium tricarbonyl 4'-oxo-terpy trimer as a luminescent molecular vessel with a removable silver stopper.
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DOI:
10.1002/anie.200900981
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发表时间:
2009-06
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影响因子:
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通讯作者:
M. Coogan;V. Fernández‐Moreira;B. Kariuki;Simon J. A. Pope;Flora L Thorp-Greenwood
M. Coogan;V. Fernández‐Moreira;B. Kariuki;Simon J. A. Pope;Flora L Thorp-Greenwood
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文献类型:
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作者:
M. Coogan;V. Fernández‐Moreira;B. Kariuki;Simon J. A. Pope;Flora L Thorp-Greenwood

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闪亮金属杯:三角形横截面的发光管,由银离子塞住(见图:Re 黄、N 蓝、O 红),由商业材料分两步形成。银离子可以被去除以形成管子,这两种物质都是小离子和分子的潜在宿主;银的封装引发了发光的变化。
Shining metal cups: A luminescent tube of triangular cross-section and stoppered by a silver ion (see picture: Re yellow, N blue, O red) is formed in two steps from commercial materials. The silver ion can be removed to give a tube, and both species are potential hosts for small ions and molecules; a change in luminescence is triggered by the encapsulation of silver.