A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te)
A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te)
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具有环戊二烯基配体的碲羰基钌 (CTe) 配合物：一系列硫族羰基配合物 [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te) 的系统研究
DOI：
10.1039/c6dt04440a
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发表时间：
2017
影响因子：
4
通讯作者：
Ishii Youichi
中科院分区：
文献类型：
--
作者：
Suzuki Ayumi;Arai Takahiro;Ikenaga Kota;Mutoh Yuichiro;Tsuchida Noriko;Saito Shinichi;Ishii Youichi
通过配体取代反应合成了第一个具有半三明治结构的硫代羰基配合物[CpRuCl(CTE)(H_2IMes)]。系统地探索了CPCE络合物[CpRuCl(CE)(H_2IMes)](E=O，S，Se，Te)的实际完整系列。CTE络合物中的碲原子可以顺利地被较轻的硫族原子取代。
The first tellurocarbonyl complex with a half-sandwich structure [CpRuCl(CTe)(H2IMes)] was synthesized by a ligand substitution reaction. The practically complete series of the CpCE complexes [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te) were systematically explored. The tellurium atom in the CTe complex could be smoothly replaced with lighter chalcogen atoms.