Kinetic electrode reactions in silver electrodeposition using a multipulse current measurement
Kinetic electrode reactions in silver electrodeposition using a multipulse current measurement
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DOI：
10.1149/1.1852435
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发表时间：
2005-01-01
影响因子：
3.9
通讯作者：
Saitou, M
中科院分区：
文献类型：
--
作者：
Saitou, M
The kinetics of electrode reactions in silver electrodeposition are investigated using a multipulse current measurement. The transient voltage drops across the anode and cathode electrodes in response to the applied multipulse currents are measured and analyzed with an analytical solution of unsteady-state equations comprising diffusion of ions, charge-transfer reactions, and a charging process of the electrochemical double layer. The measured voltage-time curves agree well with those predicted by the analytical solution. The kinetic constant, the exchange current density, and the double-layer capacitance, which characterize the kinetics of the electrode reactions, are determined. (c) 2005 The Electrochemical Society. All rights reserved.
