[{Fe(CO)3}4{SnI}6I4]2-: the first bimetallic adamantane-like cluster.
[{Fe(CO)3}4{SnI}6I4]2-: the first bimetallic adamantane-like cluster.
复制标题
[{Fe(CO)3}4{SnI}6I4]2-：第一个双金属类金刚烷簇。
作者：
S. Wolf;F. Winter;R. Pöttgen;Nils Middendorf;W. Klopper;C. Feldmann
用离子-液体法合成了第一个类金刚烷双金属簇[{Fe(CO)(3)}(4){SnI}(6)I(4)]（2-）。基于键长考虑、FT-IR和（119）Sn Mössbauer光谱以及DFT计算验证了铁和锡的价态。
Show some metal: the first bimetallic adamantane-like cluster, [{Fe(CO)(3)}(4){SnI}(6)I(4)](2-), was prepared by an ionic-liquid-based synthesis. The valence states of iron and tin were verified based on bond-length considerations, FT-IR and (119)Sn Mössbauer spectroscopy, as well as with DFT calculations.