INDUSTRIAL WATER ELECTROLYSIS - PRESENT AND FUTURE
INDUSTRIAL WATER ELECTROLYSIS - PRESENT AND FUTURE
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DOI：
10.1016/0360-3199(83)90162-3
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发表时间：
1983-01-01
影响因子：
7.2
通讯作者：
LEROY, RL
中科院分区：
文献类型：
--
作者：
LEROY, RL
在控制该过程的基本热力学和动力学约束的框架内，对目前和正在开发的从水中生产氢气的技术进行了回顾。主要关注直接电解过程。比较了碱性单极和双极、固体聚合物电解质和气相技术。结论是，在未来十年，温度低于 150°C 的碱性电解将在经济上成为首选，而气相电解则是一项具有重大但长期利益的发展。
Present and developing technologies for the production of hydrogen from water are reviewed in the framework of the fundamental thermodynamic and kinetic constraints which govern the process. Attention is directed primarily to the direct electrolysis processes. Alkaline unipolar and bipolar, solid polymer electrolyte, and vapour-phase technologies are compared. It is concluded that alkaline electrolysis at temperatures below 150°C will be economically preferred over the next decade, while vapour-phase electrolysis is a development of significant but longer-term interest.