Structure-induced carbon-13 chemical shifts : a sensitive measure of transient localized secondary structure in peptides
Structure-induced carbon-13 chemical shifts : a sensitive measure of transient localized secondary structure in peptides
复制标题
结构诱导的碳 13 化学位移：肽中瞬时局部二级结构的灵敏测量
DOI：
10.1021/ja00041a056
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发表时间：
1992
影响因子：
15
通讯作者：
D. Omecinsky
中科院分区：
文献类型：
--
作者：
M. Reily;V. Thanabal;D. Omecinsky
图1所示。红豆素的CD光谱随TFE浓度的变化。图中为bombesin在H20 （0% TFE）中的光谱。连续走线（递减220）分别为10%、15%、20%、30%和70% TFE （v/v）。平均光谱（三个独立采集）记录在0.6 mg/mL样品中，在0.1 cm的细胞中。结果从溶剂空白的光谱中减去，并用三阶多项式进行平滑处理。
Figure 1. CD spectra of bombesin as a function of TFE concentration. The spectrum of bombesin in H20 (0% TFE) is indicated. Successive traces (decreasing 220) are 10%, 15%, 20%, 30%, and 70% TFE (v/v). The averaged spectra (three independent acquisitions) were recorded on a 0.6 mg/mL sample in a 0.1-cm cell. The results were subtracted from the spectrum of a solvent blank and smoothed with a third-order polynomial.