Bidentate amidine ligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons
Bidentate amidine ligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons
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DOI：
10.1039/b411802b
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发表时间：
2004-01-01
影响因子：
4.9
通讯作者：
Iwasawa, N
中科院分区：
文献类型：
--
作者：
Aoki, M;Kaneko, M;Iwasawa, N
设计并合成了一种新型双齿脒，作为易于获得的供电子n配体，用于ni -0介导的二氧化碳与炔或烯的偶联，并且对芳基取代的内炔的羧基化也具有很高的区域选择性。
Novel bidentate amidines were designed and synthesized as easily available electron-donating N-ligands for Ni-0-mediated coupling of carbon dioxide with alkynes or allenes, and high regioselectivity was achieved even for the carboxylation of aryl substituted internal alkynes.